Structures solved using our extended NMR Crystallography approach Schematic representation of extended NMR Crystallography approach 0 1. DATZnS (NDI-salphen derivative) chem.201700324 Space group P2Cm a = 0.57 nm, b = 1.685 nm, c= 2.517 nm, α=90°, β=90° and γ=102° Structure 0 2. Perylene derivative D1A2 chem.201802288 Space group = P1 a = 1.453 nm, b = 1.55 nm, c = 1.95 nm, α=96.36°, β=107.15° and γ=108.89° Structure 0 3. Perylene derivative D2A2 chem.201802288 Space group = P-1 a = 1.17 nm, b = 1.71 nm, c = 2.01 nm, α=111.4°, β=90.8° and γ=104.7° Structure 0 4. DATZnS derivative chem.201701172 Space group = P2/c a=1.47 nm, b=1.83 nm, c=9.6 nm, α=90°, β=109° and γ=90° Structure 0 5. Gallium coordination polymer Ga(OH)2(O2C2H3) 10.1021 Space group = P2C a = 0.78875 nm, b = 0.6980 nm, c= 0.70 nm, α = 90°, β = 115.92°, γ = 90°. Structure 0 6. Aluminium coordination polymer Al(OH)2(O2C2H3) 10.1021 Space group P2C a = 0.78 nm, b = 0.67 nm, c= 0.70 nm, α = 90°, β = 116.45°, γ = 90°. Structure 0 7. Scandium acetate Sc(OH)2(O2C2H3) 10.1021 Space group a = 0.7911 nm, b = 0.7911 nm, c= 0.0866 nm, α = 90°, β = 90°, γ = 120°. Structure